Yes, I just had my ceremony there last week. You can do a ring exchange, personal vows and they don't really have a limit to the number of people that can be present. Keep in mind the inside ceremony is a tiny room; we had 10 guests, ourselves and the deputy clerk performing the ceremony. It got hot and was very cramped, but was a very short service.
The Clerk of the Circuit Court performs weddings at the DeLand Courthouse and the City Island Annex in Daytona. You can find details at: http://www.clerk.org/marriage.aspx
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