Yes, but they are mostly a fast fashion reseller so about a certain size (XL primarily) is extremely rare because those brands don't have many options about XL. Sometimes you get lucky though!
Yes is correct especially tops of which ever season their buying for.
Buffalo Exchange operates like a thrift store. So they have whatever people bring in. In regards to buying plus sizes to sell in their stores, their website says, "We're always on the lookout for plus sizes." Short answer: YES!
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