If you arrive without a reservation are there sites available on a Sunday eve?

Doesn't hurt to try and see if they have one 😁

Give the park a call they will tell you before you leave

Odds are slim. But then again there might be an opening rolling in on Sunday night assuming someone there only for the weekend has left. But as other people have noted, reservations are usually made months in advance and the middle of summer is extremely popular.

Ft. Stevens is reserved 9 months in advance all summer. There is a chance that a space will be available on a Sunday night, and it's worth trying. KOA across the street if nothing available, but it's popular too.

Off season usually yes.

Summer, no. Winter, yes.

It's always pretty full but last year a number of new comers found early vacated sites. Definitely worth trying at least.

Probably worth a phone call. I don't remember anything like overflow sites...

Probably not in the summer