I just purchased a 2019 Rav4 XLE Premium. The tires are 235 55 R19. I checked the tire pressures and found that three were 41 psi and one was 44 psi. The manual says they should be 33 or 35 psi . HELP. What should the psi on cold tires be??

Check the driver side door. Open it and look at the sticker on the column near the seat. That's you cold tire pressure. The tire pressure markings on actual tire is the maximum pressure the tire can hold. You never want to run maximum pressure on cold tires. When tires heat up by running pressure increases.

35 psi cold