Ziegist Coffee is a block and a half away. Great coffee, and all kinds of breakfast options.
Bartells, may be open that early as well? It's across the street on the upper level (2nd floor) 2nd and Jackson on the corner. Also, there is a food truck during the week outside of Amtrak. Bright Red. She does coffee and health type foods and snacks, juices, etc..
13 Coins is open 24hrs and is just a block west of King Street station. There are also a couple Starbucks within walking distance as well.
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