You can't rent to own through Enterprise but there used cars are good. My mom bought her last 2 vehicles through them. she went t through her Credit union and they made sure she received a good deal as well as a warranty( CU)
I don't believe that you can rent to own from Enterprise. I personally wouldn't want to buy a used rental car. What ever you decide to buy, make sure that you get it thoroughly checked out by a competent mechanic.
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