I think different times for different days last wed it was 1130 130 and 330 for the dolphin show had other shows too.
It depends on what you wany to see
When I was there, there were several times. The Sea Lion Show ran about every hour and the Dolphin Show ran about every 2 hours.
There are 2 different times for each one of them... A good tip is, if youur plans are getting there earlier than 11AM, there is an earlu bird ticket you can by online and is 30 dollars instead of the 39 you'd have to pay there
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