No.
Walmart does not open until 7 am.
As far as I know, no, Walmart is not open at 5am, as I believe they are still closing overnight in order to stock and deep clean/sanitize the store. This one may open at 6am, but 7am is your best bet. I would recommend calling the store yourself. The automated system should tell you the adjusted store hours without you ever having to talk to a real person (social anxiety is real, I have issues talking to people on the phone myself.)
Nope sure isn't
Look at the hours on web
Mesa, Arizona 85209 24 hours 7 day a week + Holidays
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