Not exactly but very close! The cafe is right next door to, but slightly set back from the old Peacham General Store building, where scenes from the movie were filmed. See this link for a PBS story on the town and movie at the time: https://video.vermontpbs.org/video/spitfirefixitcrowley-tvaysd/
The restaurant depicted in that film is in the adjacent store, which unfortunately is no longer operating. The café, the Spitfire Grill restaurant, and a craft guild are all essentially the same building.
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